Would this work with shoes?

it would depend on shoes, you may have success with thin strap sandals,as not much pressure on small area painted, could try out on pair of inexpensive shoes first

At this price, is it a case of 12 cans???

No, it's only one. The cans are all different prices depending on the color you get. Some cans are more expensive than others, for instance the Dover White is over $16 but it's still only one can. I don't know why the prices vary so greatly.

Can i use this spray paint on my sons cranial helmet?

you can use it if you prep helmet first sand n prime always remember two to three light coats is better than one heavy coat ,sand it 120 grit smooth then apply coats til coverage is desired

Can this be used for spraying painted rocks to seal them for leaving outside?

If referring to the clear then I can absolutely say it works quite well but it takes more coats than Aleenes clear does, to get the same longevity. I noticed that the reds family fade faster under the Krylon clear in comparison to Aleenes and the Rust-Oleum lacquer. I do always keep at least 1 can of this on hand because it truly is a very versatile clear for all of my outside art projects. Worked well when I used acrylic to paint silver alloy charms for a sun catcher when I couldn't find the charms I wanted in the right color as well!

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规格

Brand	Krylon
Color	Meringue
Finish Type	Satin
Size	12 Ounce (Pack of 1)
Item Volume	12 Fluid Ounces
Special Feature	Fast-Drying, Rust Resistant
Unit Count	12.0 Ounce
Paint Type	Acrylic
Specific Uses For Product	Interior/Exterior
Surface Recommendation	Wood,Metal,Plastic,Wicker,Glass,Ceramic,Fabric,Paper,Masonry
Indoor/Outdoor Usage	Outdoor, Indoor
Item Form	Aerosol
Included Components	Krylon COLORmaxx SATIN MERINGUE
Age Range (Description)	Adult
Is Waterproof	False
Model Name	K05570007
Package Information	Can
Color Code	Meringue
Full Cure Time	48 Hours
Coverage	25 ft²/can
Water Resistance Level	Water Resistant
UPC	724504055709
Global Trade Identification Number	00724504055709
Manufacturer	Krylon Industrial Products Group
Dry Time In Hours	1
Part Number	5570
Item Weight	16 ounces
Product Dimensions	1 x 1 x 1 inches
Country of Origin	China
Item model number	K05570007
Style	Satin
Finish	Satin
Material	Blend
Pattern	Paint and Primer
Shape	Rectangular
Thickness	2 Inches
Power Source	ac
Item Package Quantity	1
Number Of Pieces	1
Special Features	Fast-Drying, Rust Resistant
Batteries Included?	No
Batteries Required?	No