Does this interfacing need to be prewashed before sewing? Will it shrink?

The interfacing does not need to be prewashed before sewing.

I need something to use as snow/ice in applique, would this work?

I think this is too thick to use for snow or ice. You might want a lighter fleece.

Is this fusible on both sides, or on one side only?

Fusible Fleece is a one-sided fusible fleece that adds a layer of softness, body, and stability to home decorating craft, and apparel sewing. No Pinning! No Basting! No Sewing! It can be fused with fabric, cardboard, or wood. It is completely sewing machine safe. 100% Low Loft Acid-Free Polyester, 45in by-the-yard width, Packaged Size: 22in x 36in. Sewing Machine Safe

Would this be a good choice to make placemats with?

Yes you can add between two fabrics to add some stability to the placemat

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✨ Craft Your Comfort with Pellon!

VERSATILE USE - Perfect for a variety of sewing projects, from crafts to clothing.
MACHINE WASHABLE - Care for your creations with ease—gentle machine wash and tumble dry low.
DURABLE RELIABLE - Crafted from 100% polyester for long-lasting quality.
EFFORTLESS APPLICATION - Fuses easily to fabric, cardBolt, or wood—no pinning or basting required!
TRANSFORM YOUR PROJECTS - Elevate your home decor and apparel with a touch of softness and stability.

PellonPellon® 987F Fusible Fleece is a 45 x 60 inch package of low-loft fusible fleece made from 100% polyester. Designed for easy application, it eliminates the need for pinning and basting, making it ideal for home decorating, crafts, and apparel sewing projects. This product is machine washable and sewing machine safe, ensuring durability and convenience.